Alkenes and Alkynes
Alkenes are organic molecules, both hydrocarbons and molecules with
other elements substitute for the hydrogens, with at least one carbon-carbon
double bond somewhere in the structure. Because at least one carbon
bears a double bond, alkenes are said to be unsaturated.
Alkenes are named using the -ene suffix.
Alkynes are hydrocarbons that contain at least one carbon-carbon triple
bond and are also unsaturated as a result. Alkynes are named using
the -yne suffix. For both alkenes and
alkenes when there are two or more double or triple bonds in the molecule
the prefix di, tri etc. as appropriate
is used in front of the root name. The carbons along the chain are
numbered and the location of the multiple bond(s) is identified in the
name by placing a number in front of the whole molecule name. For
example, 1,3 pentadiene.
Isomers are two or more molecules that have the same molecular formula but with their individual atoms in a different arrangement. The word "isomer" comes from the Greek meaning "equal" parts. You might find it useful to think of isomers as different molecules made from the same kit or parts or atoms but with those parts attached in different ways. Some environmentally important alkenes have chlorine substituted for hydrogens in the molecule. When a chlorine atom is substitute it's location is also signaled by the carbon number to which it is attached in the name. For example, 1,1-chloroethene is distinguished from its isomer, 1,2-dichloroethene.
The double and triple bonds make alkenes and alkynes more rigid than
alkanes. As a result, they cannot pack together as closely as the
alkanes do an in general, multiple bonds lead to substances with lower
melting points.
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