Acids and Bases

There is yet another system for naming acids and bases. However, the best approach, for our purposes, is to know the names of a relatively small number of acids and bases and to recognize the features of the name that signal the presence of different numbers of atoms. The details given below are less important than being able to identify and name common acids and bases.

Acids often contain hydrogen ions, H+, in combination with an anion. The simplest acids are named by adding the prefix "hydro" to the root name of the anion followed by "ic" and the word, "acid" , as in hydrofluoric acid for the molecular formula, HF. Notice that the charges must balance for acids just as they did for ionic compounds. However, for acids, instead hydrogen ions substitute for the cation and balance the negative charge on the anion. Hydrogen sulfide is a common acid that does not follow this naming convention but shows the hydrogen ion balancing the anion charge of 2-. Its molecular formula is H2S.

Common Simple Acids

HF Hydrofluoric Acid
HCl Hydrochloric Acid
HBr Hydrobromic Acid
HI Hydroiodic Acid
HCN*
(hydrogen ion + cyanide anion)
Hydrocyanic Acid

If oxygen atoms are present in the acid molecule, the naming system needs to reflect the number of oxygens. Many nonmetals like the halogens form anions with varying numbers of oxygen atoms. The maximum possible number of oxygens is four. However, many non-metals form only one or two oxyanions. A good example is S, which forms two oxyanions -- SO4-2, the sulfate ion and SO3-2 the sulfite ion. The acid formed from these ions reflects not only the number of oxygens in the anion but also, the number of potential oxyanions that can be made with that element.

Common Oxyacids

Prefix/Suffix on Anion Number of Oxygen Atoms Example
per ------ ic acid If the element in the anion,(other than oxygen), makes anions with 4,3,2 and 1 oxygen atom then the name of the acid will be preceeded by the prefix "per" followed by the non-oxygen elements name and the suffix "ic". Perchloric Acid
HClO4
     ------ic  acid If only 3 or 2 possible oxyanions can be formed with the non-oxygen element then the oxyacid with the largest number of oxygens is named using the root name of the non-oxygen element plus the suffix "ic". Sulfuric Acid
H2S04

Nitric Acid
HNO3

Chloric Acid
HClO3

Phosphoric Acid
H3PO4

    -----ous acid If only 2 or 1 possible oxyanions can be formed with the non-oxygen element then the oxyacid with the larger number of oxygens is named using the root of the non-oxygen element in the anion and the suffix "ous" Sulfurous Acid
H2SO3

Nitrous Acid
HNO2

Chlorous Acid
HClO2

hypo ----ous acid Finally, if the non-oxygen element in the anion does form oxyanions with 4 different numbers of oxygens, the acid formed with the one oxygen is named by placing the prefix "hypo" in front of the non-oxygen element root name and the suffix "ous". Hypochlorous Acid
HClO

Most common bases contain the hydroxyl radical, OH- and a cation:

  • NaOH - Sodium Hydroxide
  • LiOH - Lithium Hydroxide
  • Ca(OH)2 -Calcium Hydroxide
  • Zn(OH)2 -Zinc Hydroxide

 
Quick Quiz: What is the name of an acid that contains bromate ion? (You may want to use the polyatomic ion calculator).

hydrobromate acid
hydrobromic acid
bromic acid
bromous acid


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